Crystal structure of a new lithium indium borate Li3InB2O6
Identifieur interne : 011603 ( Main/Repository ); précédent : 011602; suivant : 011604Crystal structure of a new lithium indium borate Li3InB2O6
Auteurs : RBID : Pascal:01-0330844Descripteurs français
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Abstract
Single crystals of synthetic Li3InB2O6 were obtained by heating a mixture of Li2CO3, In2O3 and B2O3; its formula was determined by the resolution of the structure from X-ray diffraction data. The compound is monoclinic, space group P21/n; the unit cell parameters are a = 5.168(5) Å, b = 8.899(9) Å, c = 10.099(10) Å, β = 91.112(17)°; Z = 4. The crystal structure was solved from 669 reflections until R = 0.0249; it exhibits a three-dimensional framework of vertex-sharing InO5 trigonal bipyramids and BO3 triangles, which isolates Li ions in channels. This structure is characterized by unusual oxygenated environments of In cations and of one of the three Li cations, which are forming more or less regular trigonal bipyramids. This compound melts incongruently at 827°C; the powder may be obtained by annealing at 750 °C a mixture of Li2CO3, In2O3 and B2O3.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Crystal structure of a new lithium indium borate Li<sub>3</sub>InB<sub>2</sub>O<sub>6</sub></title><author><name sortKey="Penin, Nicolas" uniqKey="Penin N">Nicolas Penin</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Réactivité et de Chimie des Solides, Université de Picardie Jules Verne, UMR CNRS 6007, 33, rue St-Leu</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Picardie</region><settlement type="city">Amiens</settlement></placeName></affiliation></author><author><name sortKey="Touboul, Marcel" uniqKey="Touboul M">Marcel Touboul</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Réactivité et de Chimie des Solides, Université de Picardie Jules Verne, UMR CNRS 6007, 33, rue St-Leu</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Picardie</region><settlement type="city">Amiens</settlement></placeName></affiliation></author><author><name sortKey="Nowogrocki, Guy" uniqKey="Nowogrocki G">Guy Nowogrocki</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRES A 8012, ENSC Lille, B.P 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">01-0330844</idno><date when="2001">2001</date><idno type="stanalyst">PASCAL 01-0330844 INIST</idno><idno type="RBID">Pascal:01-0330844</idno><idno type="wicri:Area/Main/Corpus">010C78</idno><idno type="wicri:Area/Main/Repository">011603</idno></publicationStmt><seriesStmt><idno type="ISSN">1293-2558</idno><title level="j" type="abbreviated">Solid state sci.</title><title level="j" type="main">Solid state sciences</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Channel structure</term><term>Crystal structure</term><term>Experimental study</term><term>High-resolution methods</term><term>Indium Borates</term><term>Lithium Borates</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Diffraction RX</term><term>Haute résolution</term><term>Structure cristalline</term><term>Structure tunnel</term><term>Lithium Borate</term><term>Indium Borate</term><term>6166F</term><term>Li3InB2O6</term><term>B In Li O</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Single crystals of synthetic Li<sub>3</sub>InB<sub>2</sub>O<sub>6</sub> were obtained by heating a mixture of Li<sub>2</sub>CO<sub>3</sub>, In<sub>2</sub>O<sub>3</sub> and B<sub>2</sub>O<sub>3</sub>; its formula was determined by the resolution of the structure from X-ray diffraction data. The compound is monoclinic, space group P2<sub>1</sub>/n; the unit cell parameters are a = 5.168(5) Å, b = 8.899(9) Å, c = 10.099(10) Å, β = 91.112(17)°; Z = 4. The crystal structure was solved from 669 reflections until R = 0.0249; it exhibits a three-dimensional framework of vertex-sharing InO<sub>5</sub> trigonal bipyramids and BO<sub>3</sub> triangles, which isolates Li ions in channels. This structure is characterized by unusual oxygenated environments of In cations and of one of the three Li cations, which are forming more or less regular trigonal bipyramids. This compound melts incongruently at 827°C; the powder may be obtained by annealing at 750 °C a mixture of Li<sub>2</sub>CO<sub>3</sub>, In<sub>2</sub>O<sub>3</sub> and B<sub>2</sub>O<sub>3</sub>.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1293-2558</s0></fA01><fA03 i2="1"><s0>Solid state sci.</s0></fA03><fA05><s2>3</s2></fA05><fA06><s2>4</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Crystal structure of a new lithium indium borate Li<sub>3</sub>InB<sub>2</sub>O<sub>6</sub></s1></fA08><fA11 i1="01" i2="1"><s1>PENIN (Nicolas)</s1></fA11><fA11 i1="02" i2="1"><s1>TOUBOUL (Marcel)</s1></fA11><fA11 i1="03" i2="1"><s1>NOWOGROCKI (Guy)</s1></fA11><fA14 i1="01"><s1>Laboratoire de Réactivité et de Chimie des Solides, Université de Picardie Jules Verne, UMR CNRS 6007, 33, rue St-Leu</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRES A 8012, ENSC Lille, B.P 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>3 aut.</sZ></fA14><fA20><s1>461-468</s1></fA20><fA21><s1>2001</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>11118</s2><s5>354000095458080080</s5></fA43><fA44><s0>0000</s0><s1>© 2001 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>38 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>01-0330844</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Solid state sciences</s0></fA64><fA66 i1="01"><s0>FRA</s0></fA66><fC01 i1="01" l="ENG"><s0>Single crystals of synthetic Li<sub>3</sub>InB<sub>2</sub>O<sub>6</sub> were obtained by heating a mixture of Li<sub>2</sub>CO<sub>3</sub>, In<sub>2</sub>O<sub>3</sub> and B<sub>2</sub>O<sub>3</sub>; its formula was determined by the resolution of the structure from X-ray diffraction data. The compound is monoclinic, space group P2<sub>1</sub>/n; the unit cell parameters are a = 5.168(5) Å, b = 8.899(9) Å, c = 10.099(10) Å, β = 91.112(17)°; Z = 4. The crystal structure was solved from 669 reflections until R = 0.0249; it exhibits a three-dimensional framework of vertex-sharing InO<sub>5</sub> trigonal bipyramids and BO<sub>3</sub> triangles, which isolates Li ions in channels. This structure is characterized by unusual oxygenated environments of In cations and of one of the three Li cations, which are forming more or less regular trigonal bipyramids. This compound melts incongruently at 827°C; the powder may be obtained by annealing at 750 °C a mixture of Li<sub>2</sub>CO<sub>3</sub>, In<sub>2</sub>O<sub>3</sub> and B<sub>2</sub>O<sub>3</sub>.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66F4</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Haute résolution</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>High-resolution methods</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Crystal structure</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Structure tunnel</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Channel structure</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Estructura túnel</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Lithium Borate</s0><s2>NC</s2><s2>NA</s2><s5>07</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Lithium Borates</s0><s2>NC</s2><s2>NA</s2><s5>07</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Indium Borate</s0><s2>NC</s2><s2>NA</s2><s5>08</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Indium Borates</s0><s2>NC</s2><s2>NA</s2><s5>08</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>6166F</s0><s2>PAC</s2><s4>INC</s4><s5>57</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Li3InB2O6</s0><s4>INC</s4><s5>92</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>B In Li O</s0><s4>INC</s4><s5>93</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0><s5>81</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>81</s5></fC07><fN21><s1>232</s1></fN21></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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